摘要
以TiC和TiO_2为原料在900℃烧结得到了与USTB钛电解工艺所用阳极原料类似的Ti-C-O固溶体,并对该固溶体在750℃NaCl-KCl熔盐体系中的电化学行为进行了研究。结果显示,该固溶体可以发生电化学溶解,钛元素以离子的形式进入熔盐中,碳元素和氧元素则以CO为主、CO_2为辅的气体形式析出。以该固溶体为阳极进行恒电流电解,最终在阴极得到了金属钛。
Ti-C-O solid solution similar with anode material of USTB titanium electrolysis process was obtained by sintering of TiC and TiO2 at 900 ℃. Electrochemical behavior of Ti-C-O solid solution in NaC1-KC1 molten salt at 750℃ was investigated. The results show that electrochemical dissolution occurs, with element Ti dissolving into molten salt system as metal ion, while C and O evolving into CO and CO2 gases. Metal titanium is deposited in cathode upon electrolysis with Ti-C-O solid solution as anode.
作者
王起
王泽宇
肖九三
焦树强
朱鸿民
WANG Qi WANG Ze-yu XIAO Jiu-san JIAO Shu-qiang ZHU Hong-min(School of Metallurgical and Ecological Engineering State Key Lab of Advanced Metallurgy, University of Science and Technology Beiiing, Beijing 100083, China)
出处
《有色金属（冶炼部分）》
CAS
北大核心
2017年第7期19-22,共4页
Nonferrous Metals（Extractive Metallurgy)
基金
国家高技术研究发展计划项目(2012AA062302)
国家自然科学基金青年基金资助项目(51322402)
关键词
Ti—C-O固溶体
电化学溶解
电解
钛
Ti-C-O solid solution
electrochemical dissolution
electrolysis
titanium
