摘要
以凹凸棒石为骨架,通过两步法制备了Ag@AgBr/氮化碳–凹凸棒石复合脱硫光催化剂(Ag@AgBr/FCN–ATP)。研究表明:ATP表面形成了均匀的FCN膜,Ag@AgBr粒子均匀地负载在ATP–FCN表面。与Ag@AgBr相比,Ag@AgBr/FCN–ATP具有大的比表面积和高的可见光响应及分离光生空穴–电子能力。以二苯并噻吩(DBT)为目标硫化物,考察了在可见光下催化剂对DBT的氧化脱除能力。结果表明:Ag与DBT中的S形成σ配位键吸附作用,Ag@AgBr和FCN–ATP之间的异质结构和协同效应有效地促进光生电子的传输且抑制空穴–电子复合。当光照时间为180 min时,Ag@AgBr/FCN–ATP的脱硫率可达85.2%。
Ag@AgBr/C3N4-attapulgite (Ag@AgBr/FCN-ATP) composite photocatalyst for desulfurization was fabricated by a two-step method using ATP as a skeleton. The results show that Ag@AgBr particles are uniformly loaded on the surface of ATP-FCN and FCN membrane is coated on the surface of ATP. Compared to Ag@AgBr, Ag@AgBr/FCN-ATP composite has greater specific surface area, higher visible light response and enhanced hole-electron separation ability. The photocatalytic desulfurization of dibenzothiophene (DBT) under visible light indicates that Ag@AgBr/FCN-ATP can adsorb DBT via σ coordinate interaction between Ag and S atoms, and the heterostructure and the synergistic effect between Ag@AgBr and FCN-ATP can transfer the electron, leading to suppress the electron-hole recombination. After 180 min irradiation, the desulfurization rate of Ag@AgBr/FCN-ATP reaches 85.2%.
出处
《硅酸盐学报》
EI
CAS
CSCD
北大核心
2017年第7期1024-1030,共7页
Journal of The Chinese Ceramic Society
基金
江苏省科技支撑计划(BE2014100)
江苏省先进催化与绿色制造协同创新中心人才支持项目(ACGM2016-06-11)
中央高校基本科研业务费专项资金(30916014103)
关键词
凹凸棒石
氮化碳
银@溴化银
光催化脱硫
attapulgite
carbon nitride
silver@silver bromide
photocatalytic desulfurization