摘要
The corrosion behavior of copper exposed in a simulated coastal-industrial atmosphere has been investigated using weight loss measurement, scanning electron microscopy, X-ray diffraction, potentiodynamic polarization and in-situ electrochemical impedance spectroscopy（EIS） with micro-distance electrodes.The results show that corrosion kinetics follows the empirical equation D = Atn. The main corrosion products are composed of Cu_2O, Cu_2Cl（OH）_3 and Cu_4Cl_2（OH）_6. A two-layer structure comprising a loose outer layer and a compact inner layer forms the corrosion products during corrosion process. SO_2 has been found to promote the formation of Cu_4Cl_2（OH）_6.
The corrosion behavior of copper exposed in a simulated coastal-industrial atmosphere has been investigated using weight loss measurement, scanning electron microscopy, X-ray diffraction, potentiodynamic polarization and in-situ electrochemical impedance spectroscopy（EIS） with micro-distance electrodes.The results show that corrosion kinetics follows the empirical equation D = Atn. The main corrosion products are composed of Cu_2O, Cu_2Cl（OH）_3 and Cu_4Cl_2（OH）_6. A two-layer structure comprising a loose outer layer and a compact inner layer forms the corrosion products during corrosion process. SO_2 has been found to promote the formation of Cu_4Cl_2（OH）_6.
基金
financially supported by the Technology Projects from China Southern Power Grid (K-GD2014-0532)
the National Natural Science Foundation of China (Nos. 51131007 and 51401222)
