摘要
We investigate the high resolution photoassociation spectra of ^（85）Rb_2 molecules in 0~＋_u long range state below the（5S_（1/2）＋ 5P_（1/2）） asymptote. The ^（85）Rb atomic samples are trapped in a dark magneto–optical trap（MOT） and prepared in the dark state. With the help of trap loss technique, we obtain considerable photoassociation spectroscopy with rovibrational resolution, some of which have never been observed before. The observed spectrum is fitted by a rigid rotation model, and the rotational constants of ultracold ^（85）Rb_2 molecule in long range 0~＋_u are obtained for different vibrational states. By applying the Le Roy–Bernstein method, we assign the vibrational quantum numbers and derive C_3 coefficient, which is used to obtain the potential energy curve.
We investigate the high resolution photoassociation spectra of ^（85）Rb_2 molecules in 0~＋_u long range state below the（5S_（1/2）＋ 5P_（1/2）） asymptote. The ^（85）Rb atomic samples are trapped in a dark magneto–optical trap（MOT） and prepared in the dark state. With the help of trap loss technique, we obtain considerable photoassociation spectroscopy with rovibrational resolution, some of which have never been observed before. The observed spectrum is fitted by a rigid rotation model, and the rotational constants of ultracold ^（85）Rb_2 molecule in long range 0~＋_u are obtained for different vibrational states. By applying the Le Roy–Bernstein method, we assign the vibrational quantum numbers and derive C_3 coefficient, which is used to obtain the potential energy curve.
基金
supported by the National Natural Science Foundation of China(Grant Nos.61675120,11434007,and 61378015)
the National Natural Science Foundation of China for Excellent Research Team(Grant No.61121064)
the Shanxi Scholarship Council of China
the PCSIRT(Grant No.IRT 13076)
