摘要
By using the statistical mechanics, the pressure tensor for the multi component fluid mixture is derived. With the help of the classical density functional theory, profiles of the pressure components are calculated, and the influence of the total volume fraction, ratio of volume fraction, and size asymmetry on the pressure are studied. In addition, our results show that for the mixture confined in the hard cavity, the pressure shows a discontinuity near the cavity wall. However, in the soft cavity condition, the discontinuity disappears.
By using the statistical mechanics, the pressure tensor for the multi component fluid mixture is derived. With the help of the classical density functional theory, profiles of the pressure components are calculated, and the influence of the total volume fraction, ratio of volume fraction, and size asymmetry on the pressure are studied. In addition, our results show that for the mixture confined in the hard cavity, the pressure shows a discontinuity near the cavity wall. However, in the soft cavity condition, the discontinuity disappears.
基金
supported by the National Natural Science Foundation of China(Grant No.21503077)
the Fundamental Research Fund for the Central Universities of China(Grant Nos.2016MS156 and 13MS105)
the Technology Research and Development Program of Hebei Province,China(Grant No.13213704)
the Program of Study Abroad for Young Teachers by Agricultural University of Hebei
