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Preparation of chitosan/N-doped graphene natively grown on hierarchical porous carbon nanocomposite as a sensor platform for determination of tartrazine

Preparation of chitosan/N-doped graphene natively grown on hierarchical porous carbon nanocomposite as a sensor platform for determination of tartrazine
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摘要 In this work,the chitosan and N-doped graphene natively grown on hierarchical porous carbon(N-PC-G/CS) nanocomposite was obtained by ultrasonic method,as a novel sensor platform for determination of tartrazine(TT).The nanocomposite as prepared had well dispersivity in water and excellent conductivity.The N-PC-G/CS nanocomposite was characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption,fourier transform infrared(FTIR) and electrochemical impedance spectroscopy(EIS).The application of N-PC-G/CS for determination of tartrazine(TT) was investigated by chronocoulometry(CC),cyclic voltammetry(CV) and differential pulse voltammetry(DPV).Under optimized conditions,the sensor displayed a sensitive response to TT within a wide concentration range of 0.05-15.0 μmol/L,the detection limits is 0.036 μmol/L(S/N = 3).Furthermore,this nanocomposite could be efficiently applied for determination of TT in soft drink samples. In this work,the chitosan and N-doped graphene natively grown on hierarchical porous carbon(N-PC-G/CS) nanocomposite was obtained by ultrasonic method,as a novel sensor platform for determination of tartrazine(TT).The nanocomposite as prepared had well dispersivity in water and excellent conductivity.The N-PC-G/CS nanocomposite was characterized by scanning electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption,fourier transform infrared(FTIR) and electrochemical impedance spectroscopy(EIS).The application of N-PC-G/CS for determination of tartrazine(TT) was investigated by chronocoulometry(CC),cyclic voltammetry(CV) and differential pulse voltammetry(DPV).Under optimized conditions,the sensor displayed a sensitive response to TT within a wide concentration range of 0.05-15.0 μmol/L,the detection limits is 0.036 μmol/L(S/N = 3).Furthermore,this nanocomposite could be efficiently applied for determination of TT in soft drink samples.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2017年第7期1492-1498,共7页 中国化学快报(英文版)
基金 supported by the National Natural Science Foundation of China(Nos.21165016,21175108,21265018) the Science and Technology Support Projects of Gansu Province(Nos.1011GKCA025,090GKCA036,1208RJZM289)
关键词 Porous carbon Graphene Chitosan Sensor Tartrazine Porous carbon Graphene Chitosan Sensor Tartrazine
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