摘要
利用溶剂热法合成了新型甲酸钴配位聚合物[Co(COOH)_2·2H_2O]。采用单晶X射线、粉末X射线(XRD)、元素分析、红外光谱(IR)、热重分析(TGA)表征了该配合物的结构。结果表明[Co(COOH)_2·2H_2O]晶体属单斜晶系,P_(21)c空间群,a=8.8334(11),b=7.2816(9),c=9.6103(12),α=90.00,β=97.666(2),γ=90.00,V=612.62-3,Z=4。
A novel cobalt formate coordination polymer [Co（COOH）2·2H2O] was successfully synthesized under solvothermal condition. The compound was characterized by single-crystal X-ray analysis, powder X-ray diffraction（XRD）, elemental analysis, infrared（IR） spectroscopy and thermal gravimetric analysis（TGA）. The results show that synthesized [Co（COOH）2·2H2O] has monoclinic structure with space group P（21）/c,a=8.8334（11）？,b=7.2816（9）？, c=9.6103（12）？,α=90.00,β=97.666（2）,γ=90.00,V=612.62？-3,Z=4.
出处
《当代化工》
CAS
2017年第7期1361-1363,共3页
Contemporary Chemical Industry
关键词
甲酸钴
配位聚合物
晶体结构
Cobalt（Ⅱ） formate
Coordination polymer
Crystal structure
