准东煤燃烧过程中Na/Ca/Fe对结渣行为影响的机理研究

Effect of Na/Ca/Fe on Slagging Behavior of Zhundong Coal During Combustion Process

在一维沉降炉实验系统中进行准东煤燃烧实验,采用非冷却的取样探针在不同烟气温度下收集灰样并进行分析,以获得烟气中不同无机成分在结渣前的形态及灰颗粒间的结合方式.结果表明:当烟气温度为1 000℃时,存在熔融态Na的硅酸盐、硅铝酸盐和CaSO_4,这些熔融态的灰颗粒会撞击、黏附在管壁上;当渣层逐渐增厚时,表面温度升高,可能在渣层表面形成熔融态的膜,以捕捉其他灰颗粒;Fe具有助熔作用,可与硅钙镁铝钠体系形成低温共熔物,当Fe_2O_3颗粒撞击到焦体熔融表面时,其助熔作用会降低焦体表面的熔点而形成新的焦体.

Combustion experiments were conducted for Zhundong coal in a drop tube furnace, where ash particles were collected at different flue gas temperatures by a sampling probe in un-cooled mode, so as to analyze the status of different inorganic components in the flue gas before slagging, as well as to obtain the combination mode of ash particles. Results show that at the temperature of 1 000℃, the ash particles con- taining sodium silicates, sodium aluminosilicates, and calcium sulphates keep in molten state, which im- pact and adhere on the tube wall; with the rise of slag layer thickness, the surface temperature increases, leading to the formation of molten film on the slag layer to further capture other ash particles; Fe species are fluxing agents, which may react with Si, A1, Mg, Na and Ca system to form the low temperature eu- tectic; when particles rich in Fe2 03 impact the molten deposit surface, a new layer of slag would be created due to the reduced melting point of deposit surface caused by the fluxing action of Fe203.