摘要
采用柚子皮作为生物吸附剂,在对模拟的放射性废水的单种金属元素溶液吸附研究中,柚子皮表现出对镧锕系金属离子的高效吸附;在对多种金属元素的混合溶液吸附研究中,柚子皮表现出对钍离子的高效选择性吸附。结果表明,Th^(4+)的质量浓度100 mg/L、初始pH 4、吸附剂浓度3.5 g/L、粒径150~200目、吸附时间120 min时,柚子皮吸附剂对Th^(4+)的去除率可达94.87%,最大吸附量43.01 mg/g。柚子皮对Th^(4+)的吸附行为符合Langmuir等温模型,吸附属于单分子层吸附。柚子皮对钍(IV)的吸附行为符合拟二级动力学模型。
Using the pummelo peel as biological adsorbent, in the study of radioactive waste of a single metal element solution adsorption, pummelo peel showed a strong adsorption of lanthanide actinium metal ions, especially in a variety of metal elements mixed solution adsorption study, it was found that the pum-melo peel exhibited an efficient for selective adsorption of thorium ions. The results show that:when the concentration of Th4+ was 100 mg/L,the initial pH was 4,adsorbent concentration 3.5 g/L,particle size of 150 -200 mesh,the adsorption time is 120 min,the pummelo peel adsorbent for Th4+ removal rate can reach 94. 87% ,the maximum adsorption capacity is 43.01 mg/g. The adsorption behavior of the pummelo peel on Th4+ accorded with the Langmuir isothermal model, and the adsorption was monomolecular ad-sorption. The pseudo-second-order kinetics equation can better describe the adsorption behavior of the pummelo peel on thorium (IV)-
出处
《应用化工》
CAS
CSCD
北大核心
2017年第9期1742-1746,共5页
Applied Chemical Industry
基金
重庆市科委基金(cstc2014yykf A20003)
重庆工商大学研究生创新型科研项目(yjscxx2017-066-66)
重庆工商大学学生科技创新基金资助项目(173020
179028)
关键词
废水处理
柚子皮吸附剂
钍离子
吸附等温线
吸附动力学
wastewater treatment pummelo peel adsorbent thorium ion adsorption isotherm adsorp-tion kinetics