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Tannic Acid as a Polyphenol Material-Assisted Synthesis of Cyclic Carbonates Using CO2 as a Feedstock: Kinetic Characteristic and Mechanism Studies 被引量:3

Tannic Acid as a Polyphenol Material-Assisted Synthesis of Cyclic Carbonates Using CO2 as a Feedstock: Kinetic Characteristic and Mechanism Studies
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摘要 Tannic acid (TA)/KI as a cheap,green,highly-efficient,biocompatible,and recyclable catalytic system represents the excellent synergistic effect in the cycloaddition reactions of CO2 and epoxides under solvent-free conditions,which is originated from hydrogen bonding between the hydrogen atoms of phenolic hydroxyl groups within TA and the oxygen atom of the epoxide.Therefore,it is considerable to be a sustainable methodology for the utilization of bio-resources. Tannic acid (TA)/KI as a cheap,green,highly-efficient,biocompatible,and recyclable catalytic system represents the excellent synergistic effect in the cycloaddition reactions of CO2 and epoxides under solvent-free conditions,which is originated from hydrogen bonding between the hydrogen atoms of phenolic hydroxyl groups within TA and the oxygen atom of the epoxide.Therefore,it is considerable to be a sustainable methodology for the utilization of bio-resources.
机构地区 School of Chemistry
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2017年第5期659-664,共6页 中国化学(英文版)
关键词 carbon dioxide cyclic carbonate tannic acid kinetic study cooperative effect carbon dioxide, cyclic carbonate, tannic acid, kinetic study, cooperative effect
分类号 O [理学]
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