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Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Tri meth oxysi lane 被引量:3

Study of Karstedt's Catalyst for Hydrosilylation of a Wide Variety of Functionalized Alkenes with Triethoxysilane and Tri meth oxysi lane
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摘要 The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Pt,(H2C=CHSiMe2OSiMe2CH = CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity. The hydrosilylation is one of the most important methods for the synthesis of organosilicon compounds. Karstedt's catalyst [Pt,(H2C=CHSiMe2OSiMe2CH = CH2)m] is a kind of platinum catalyst which is widely used in the hydrosilylation. In this paper, we studied the catalytic activity of Karstedt's catalyst for the hydrogenation of olefins and especially aminated alkenes with trimethoxysilane and triethoxysilane, and demonstrated the excellent performance in terms of the yield and selectivity.
出处 《Chinese Journal of Chemistry》 SCIE CAS CSCD 2017年第8期1227-1230,共4页 中国化学(英文版)
基金 Acknowledgement This work was supported by the National Natural Science Foundation of China under grant No. 21371096.
关键词 Karstedt's catalyst HYDROSILYLATION aminated alkenes selectivity Karstedt's catalyst, hydrosilylation, aminated alkenes, selectivity
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