摘要
A heterogeneous metal-organic cage based on Rh-Rh bonds [Rh4（pbeddb）4（H2O）2（DMAC）2] （MOC-18; pbeddb2- = 3,3＇-（1,3-phenylenebis（ethyne-2,1-diyl））dibenzoate） was applied to the N-- H insertion reactions with diazo compounds. This method offered an environmentally friendly and highly efficient approach for C--N bond formation.
A heterogeneous metal-organic cage based on Rh-Rh bonds [Rh4（pbeddb）4（H2O）2（DMAC）2] （MOC-18; pbeddb2- = 3,3＇-（1,3-phenylenebis（ethyne-2,1-diyl））dibenzoate） was applied to the N-- H insertion reactions with diazo compounds. This method offered an environmentally friendly and highly efficient approach for C--N bond formation.
