摘要
在NH_3-NH_4Cl-H_2O体系下加入组合添加剂进行锌电积,考察极距、电流密度、电积时间和初始锌离子浓度对电流效率和阴极锌表面形貌的影响。结果表明,在极距3cm、电流密度400A/m^2、电积时间4h、初始锌离子浓度40g/L的较优条件下,锌电积电流效率超过95%,阴极锌表面致密平整。
Zinc was electrodeposited in NHa-NH4Cl-H2O system with combined additives. Effects of electrode distance, current density, electro-winning time, and initial concentration of zinc ions on surface morphology and current efficiency of zinc electro-winning were investigated. The results show that current efficiency is 95% above with smooth and dense surface morphology of cathode zinc under the optimum conditions including electrode distance of 3 cm, currency density of 400 A/m2 , initial concentration of zinc ions of 40 g/L, and electro-winning time of 4 h.
作者
温功玉
王瑞祥
廖根
郭跃东
毛继勇
熊家春
钟婷
WEN Gong yu WANG Rui-xiang LIAO Gen MAO Ji-yong XIONG Jia-chun ZHONG Ting(School of Metallurgical and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China Ganzhou Nonferrous Metallurgy Research, Ganzhou 341000, Jiangxi, China)
出处
《有色金属(冶炼部分)》
CAS
北大核心
2017年第10期10-14,共5页
Nonferrous Metals(Extractive Metallurgy)
基金
国家自然科学基金资助项目(51164011)
关键词
氨性体系
锌电积
添加剂
表面形貌
电流效率
ammonia system
zinc electrodeposition
additives
surface morphology
current efficiency