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Synthesis of a Newly Modified Poly-H8-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylalumininm to Aromatic Aldehydes

Synthesis of a Newly Modified Poly-H8-BINOL Ligand and Its Applications in the Asymmetric Addition of Triethylalumininm to Aromatic Aldehydes
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摘要 A new H8-BINOL polymer was synthesized by radical polymerization and proved to be an effective cata- lyst in enantioselective addition of triethylaluminium to aromatic aldehydes in the presence of titanium isopropoxide. The polymer can be prepared with simple steps and reused without losing its enantioselectivity and catalytic activity. A new H8-BINOL polymer was synthesized by radical polymerization and proved to be an effective cata- lyst in enantioselective addition of triethylaluminium to aromatic aldehydes in the presence of titanium isopropoxide. The polymer can be prepared with simple steps and reused without losing its enantioselectivity and catalytic activity.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2017年第5期742-745,共4页 高等学校化学研究(英文版)
基金 Supported by the Higher Education Doctoral Science Foundation of China(No.20134301110004).
关键词 H8-BINOL Radical polymerization TRIETHYLALUMINIUM Asymmetric addition ENANTIOSELECTIVITY H8-BINOL Radical polymerization Triethylaluminium Asymmetric addition Enantioselectivity
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