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正丁醛歧化制备丁酸丁酯的工艺流程研究 被引量:1

Synthesis of Butyl Butyrate by Disproportionation of n-butyraldehyde with One-step Procedure
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摘要 正丁醛作为丁辛醇装置的中间产物,拥有丰富的原料来源。以正丁醛歧化酯化法合成丁酸丁酯的工艺路线为研究对象,对催化剂体系、反应条件等进行了优化,使反应转化率达到92%,以上,选择性超过85%,。最后,结合小试研究成果,制定了一套中试装置产品分离精制方案,为正丁醛一步法生产丁酸丁酯的工业化提供了理论依据和研究基础。 As an intermediate product of OXO plants, n-butyraldehyde has abundant source of raw materials. The synthe- sis of butyl butyrate was studied by disproportionation of n-butyraldehyde. The catalyst system and reaction conditions were optimized. Then, a conversion ratio over 92% and a selectivity more than 85% were achieved. Finally, according to these results, a pilot separation program for butyraldehyde was developed, which would provide a theoretical guidance and re- search basis for the industrialization of butyl butyrate production by a one-step procedure.
作者 王松 王海 李云辉 高进 杜文强 WANG Song WANG Hai LI Yunhui GAO Jin DU Wenqiang(TianjinBohuaYongliChemicallndustryCo., Ltd., Tianjin300452, China Dalian Institute of Chemical Physics, Chinese Academy of Siences, Dalian 116023, Liaoning Province, China)
出处 《天津科技》 2017年第10期79-82,86,共5页 Tianjin Science & Technology
关键词 正丁醛 丁酸丁酯 歧化酯化 丁辛醇 流程模拟 n-butyraldehyde butyl butyrate disproportionation and esterification OXO plant process simulation
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