四氮唑-1-乙酸及其衍生物金属构筑配合物的研究进展

Advances on Tetrazole-1-acetic Acid-Based Metal Coordination Polymers

四氮唑-1-乙酸(Htza)类有机配体具有良好的配位能力和多样的配位形式,在配位化学领域得到了迅速且广泛的研究。本文总结了基于四氮唑-1-乙酸配体构筑的金属配合物的研究进展和这些金属配合物的结构特征,讨论了基于四氮唑-1-乙酸构筑的金属配合物在光学、磁性、催化方面的应用,并对这类配体的发展前景进行了展望。

Tetrazole-1-acetic acids（ Htza） as a class of organic ligands with good coordination abilities and various coordination fashions have gained rapid and extensive studies in coordination chemistry. This article reviewed the research advances on the synthesis and structure characterization of tetrazole-1-acetic acid coordinated metal complexes,and discussed the fluorescent,magnetic,and catalytic applications of tetrazole-1-acetic acid-based coordination polymers. Finally,research prospects of coordination polymers based on tetrazole-1-acetic acid derivatives were discussed.