C—S键构筑的研究进展

Progress in the Formation of C—S Bond

C—S键的构筑是有机合成的基础,对于天然产物、重要生物分子的合成和功能性材料的开发等具有重要作用,因此受到了广泛的关注.对近年来C—S键的构筑方面取得的进展进行了归纳,根据C—S键的成键方式不同,分别从C—H键活化、脱羧偶联反应、Ullmann反应这三个方面进行了总结,并从配体类型对Ullmann C—S成键展开论述.

The construction of C—S bond is the fundamental of organic synthesis, which plays an important role in the synthesis of natural products, biomolecules and functional materials. Thus, it has been received much attention. Base on the different C—S bonding method, the C—H bond activation, decarboxylation coupling reaction and Ullmann reaction are introduced. The ligands of Ullmann C—S coupling are also summarized.