摘要
对一步反应合成二氯(五甲基环戊二烯基)合钌(Ⅲ)聚合物[(C5Me5)RuCl_2]_n的方法进行改进,将原料中水合三氯化钌与配体的摩尔比调整为1:1.66,采用氩气保护的无水无氧制备装置,产率达到80%。元素分析、红外光谱(IR)、核磁共振(~1H-NMR)的表征结果证实了目标产物结构。
[（C5Me5）RuCl2]n has been synthesized through one-step reaction. Preparation method has been improved and optimized, thus the productivity was up to 80%, which was higher than reproted values of literature. Structure of the complexes have been represented by the structural analytical methods like elemental analysis, IR,1H-NMR, then their chemical construction were confirmed finally.
出处
《贵金属》
CAS
CSCD
北大核心
2017年第B10期120-123,共4页
Precious Metals
基金
云南省省院省校科技合作项目(2015IB019)
昆明市科技计划项目(2016-1-G-03331)
