摘要
在四氢呋喃介质中,将1,5-环辛二烯氯化铱(Ⅰ)二聚体([Ir(cod)Cl]_2)与乙酰丙酮加热回流,一步合成了1,5-环辛二烯(乙酰丙酮)铱(Ⅰ)[Ir(acac)(cod)],产率88.6%。用元素分析、红外光谱(IR)和核磁共振(~1H-NMR、^(13)C-NMR)等分析,结果表明产物为目标化合物。
Ir（acac）（cod）was synthesized in one-step process from [Ir（cod）Cl]2 in tetrahydrofuran by adding Hacac as the anion ligand. The yield was 88.6%. Structure of the complexes have been represented by the structural analytical methods like elemental analysis,1H-NMR, 13C-NMR, IR, then their chemical construction were confirmed finally.
出处
《贵金属》
CAS
CSCD
北大核心
2017年第B10期124-126,共3页
Precious Metals
基金
云南省基础研究计划项目(2017FD212)
云南省省院省校科技合作项目(2015IB019)
昆明市科技计划项目(2016-1-G-03331)
