摘要
通过改变Cu/Zn质量比,用浸渍法制备了一系列的CuZnAl催化剂。采用X射线衍射(XRD)、H_2程序升温还原(H_2-TPR)、氮吸附(BET)、NH_3程序升温脱附(NH_3-TPD)、扫描电子显微镜(SEM)等对催化剂的结构进行了表征,并在固定床上考察了不同催化剂用于CO加氢反应的催化活性。结果表明:Cu/Zn含量确实对催化剂的结构和活性有显著的影响。当Cu/Zn质量比为2∶1时,催化剂的比表面积和最可几孔径最大、粒子分散性最好,且在CO加氢反应中表现出最高的二甲醚选择性。
A series of CuZnAl catalysts were prepared through impregnation method by changing the mass ratio of Cu/Zn.The structures of the catalysts were characterized by XRD,H2-TPR,BET,TPD and SEM,and the catalytic activity of different catalysts for CO hydrogenation was investigated in a fixed bed reactor.The results showed that Cu/Zn content does have a significant impact on the structure and activity of the catalyst.When the mass ratio of Cu/Zn is 2 ∶ 1,the catalyst showed the biggest specific surface area and pore size,the best particle dispersion and the highest selectivity of DME in CO hydrogenation.
作者
崔燕
栾春晖
贾磊
黄伟
CUI Yah LUAN Chun-hui JIA Lei HUANG Wei(Key Laboratory of Coal Science and Technology of Education Ministry and Shanxi Province, Taiyuan University of Technology, Taiyuan 030024, Chin)
出处
《天然气化工—C1化学与化工》
CSCD
北大核心
2017年第5期22-26,39,共6页
Natural Gas Chemical Industry
基金
国家自然科学基金(21336006)