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The hydrogen and oxygen isotopic compositions of hydroxyl in clay mineral from a weathering profile: New proxies for paleo-climate change?

The hydrogen and oxygen isotopic compositions of hydroxyl in clay mineral from a weathering profile: New proxies for paleo-climate change?
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摘要 Recent studies suggest that the hydrogen and oxygen isotopic compositions of clay minerals can indicate paleoclimate.Here,we report mineralogy and stable isotopic records(d D and δ^(18)O_(OH))of a weathering profile located in the Fujian Province,aiming to validate whether hydroxyl stable isotopes can indicate paleo-precipitation and paleo-temperature.Our results indicate that the d D and δ^(18)O_(OH)changes in the kaolinite hydroxyl of the weathering profile are basically determined by the isotopic composition of paleo-meteoric water and paleotemperature,respectively.Nevertheless,whether the d D and δ^(18)O_(OH)of kaolinite can quantitatively indicate paleo-precipitation and paleo-temperature needs to be verified further,and especially,the structural oxygen isotopic composition that is the essential element for the kaolinite formation temperature calculation has to be constrained in future work. Recent studies suggest that the hydrogen and oxygen isotopic compositions of clay minerals can indicate paleoclimate.Here,we report mineralogy and stable isotopic records(d D and δ^18O(OH))of a weathering profile located in the Fujian Province,aiming to validate whether hydroxyl stable isotopes can indicate paleo-precipitation and paleo-temperature.Our results indicate that the d D and δ^18O(OH)changes in the kaolinite hydroxyl of the weathering profile are basically determined by the isotopic composition of paleo-meteoric water and paleotemperature,respectively.Nevertheless,whether the d D and δ^(18)O(OH)of kaolinite can quantitatively indicate paleo-precipitation and paleo-temperature needs to be verified further,and especially,the structural oxygen isotopic composition that is the essential element for the kaolinite formation temperature calculation has to be constrained in future work.
出处 《Acta Geochimica》 EI CAS CSCD 2017年第3期370-373,共4页 地球化学学报(英文)
基金 funded by the National Natural Science Foundation of China(NSFC)(Grant Nos.41225020 and41376049) National Programme on Global Change and Air-Sea Interaction(GASI-GEOGE-03)
关键词 氢氧同位素组成 古气候变化 风化剖面 粘土矿物 稳定同位素 大气降水 同位素记录 组成测定 Weathering profile Hydrogen and oxygen isotopes Hydroxyl Kaolinite
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