摘要
A fluorescence-enhanced probe PY, which is based on integration of pyrene moiety and amino acid group,was developed for the orthogonal recognition of In3＋ and Al3＋ by the quick formation of 1：1 complex. PY shows high selectivity and sensitivity for In3＋ in NaOAc/HOAc（pH 4.8） buffer solution but rather for Al3＋ in methanol. Moreover, this probe shows good cell permeability, and the recognition of In3＋ by PY was successfully applied in bioimaging, which was the first example for detection of this metal ion in living cells.
A fluorescence-enhanced probe PY, which is based on integration of pyrene moiety and amino acid group,was developed for the orthogonal recognition of In3＋ and Al3＋ by the quick formation of 1：1 complex. PY shows high selectivity and sensitivity for In3＋ in NaOAc/HOAc（pH 4.8） buffer solution but rather for Al3＋ in methanol. Moreover, this probe shows good cell permeability, and the recognition of In3＋ by PY was successfully applied in bioimaging, which was the first example for detection of this metal ion in living cells.
基金
supported by the National Natural Science Foundation of China (Nos. 21572091 and 21472075)
the Fundamental Research Funds for the Central Universities (No. lzujbky-2016-51) by MoE of China
