摘要
A novel magnetic electrochemical sensor was designed for determination of lead ions based on gold na- noparticles（AuNPs）@SiO2@Fe3O4/nitrogen-doped graphene（NG） composites functionalized with L-cysteine. The Au@SiO2@Fe3O4/NG was synthesized by the electrostatic adsorption between AuNPs and SiO2-coated Fe304 NPs（SiO2@Fe304） and the amide bond between Au@SiO2@Fe3O4 and NG. L-Cysteine was successfully functionalized on the surface of Au@SiO2@Fe3O4/NG nanocomposites via the S--Au bond between L-cysteine and AuNPs. Owing to numerous active sites in L-cysteines and high conductivity of Au@SiO2@Fe3O4/NG composites, the pro- posed electrochemical sensor exhibited a well-distributed nanostructure and high responsivity toward Pb（II）. The sensor linearly responded to Pb2＋ concentration in the range of 5-80 μg/L with a detection limit of 0.6 μg/L, indicating that this L-cysteine functionalized Au@SiO2@Fe3O4/NG composite could be a promising candidate material for the detection of Pb2＋.
A novel magnetic electrochemical sensor was designed for determination of lead ions based on gold na- noparticles（AuNPs）@SiO2@Fe3O4/nitrogen-doped graphene（NG） composites functionalized with L-cysteine. The Au@SiO2@Fe3O4/NG was synthesized by the electrostatic adsorption between AuNPs and SiO2-coated Fe304 NPs（SiO2@Fe304） and the amide bond between Au@SiO2@Fe3O4 and NG. L-Cysteine was successfully functionalized on the surface of Au@SiO2@Fe3O4/NG nanocomposites via the S--Au bond between L-cysteine and AuNPs. Owing to numerous active sites in L-cysteines and high conductivity of Au@SiO2@Fe3O4/NG composites, the pro- posed electrochemical sensor exhibited a well-distributed nanostructure and high responsivity toward Pb（II）. The sensor linearly responded to Pb2＋ concentration in the range of 5-80 μg/L with a detection limit of 0.6 μg/L, indicating that this L-cysteine functionalized Au@SiO2@Fe3O4/NG composite could be a promising candidate material for the detection of Pb2＋.
基金
Supported by the National Natural Science Foundation of China（No.31101284）, the Graduate Research and Innovation Foundation of Chongqing, China（No.CYS17017）, the Fundamental Research Funds for the Central Universities of China （Nos. CQDXWL-2012-034, CQDXWL-2012-035, CDJPY12220001） and the Chongqing University Student Research Training Program, China（Nos.CQU-SRTP-2015497, CQU-SRTP-2015502）.
