摘要
Flower-like Co3O4 hierarchical microspheres composed of self-assembled porous nanoplates were pre- pared by employing Pluronic F127 block-copolymer as template. The samples were characterized by powder X-ray diffraction（PXRD）, scanning/transmission electron microscopy（SEM/TEM）, and nitrogen adsorption-desorption at 77 K. The results show that the catalytic activity of Co3O4 nanoflowers for the combustion of ventilation air methane is higher than that of commercial Co3O4. The superior catalytic performance of this material can be related to its dominantly exposed {112} crystal planes and higher content of surface Co3＋.
Flower-like Co3O4 hierarchical microspheres composed of self-assembled porous nanoplates were pre- pared by employing Pluronic F127 block-copolymer as template. The samples were characterized by powder X-ray diffraction（PXRD）, scanning/transmission electron microscopy（SEM/TEM）, and nitrogen adsorption-desorption at 77 K. The results show that the catalytic activity of Co3O4 nanoflowers for the combustion of ventilation air methane is higher than that of commercial Co3O4. The superior catalytic performance of this material can be related to its dominantly exposed {112} crystal planes and higher content of surface Co3＋.
基金
Supported by the National Natural Science Foundation of China（Nos.21671147, 51203109） and the Funding of the State Key Laboratory of Coal and Coalbed Methane Co-mining, China.
