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甲酸锶的合成及表征 被引量:1

Synthesis and characterization of strontium complex based on formic acid
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摘要 通过溶剂热法合成了一新的锶的配合物[Sr(HCOO)_2]n,并用X射线单晶衍射对该配合物进行了结构表征,还通过X-射线粉末衍射、红外光谱、热重分析,对配合物进行了表征。单晶衍射结果表明,配合物为三维微孔结构;热稳定性结果表明,在温度低于417℃时,配合物是稳定的,当温度高于417℃之后,配合物逐渐分解且结构坍塌。 A new strontium complex [Sr(HCOO)2]n, was synthesized by solvothermal reaction method and characterized by X-ray single crystal diffraction. The complex was also characterized by X-ray powder diffraction, infrared spectra and thermogravimetric analysis. Single crystal diffraction result showed that the complex was a three-dimensional porous structure. The thermal analysis showed that the complexes were stable below 417℃, when the temperature was above 417℃, the complex decomposed and the structure collapsed.
出处 《黄冈师范学院学报》 2017年第6期33-36,共4页 Journal of Huanggang Normal University
基金 湖北省自然科学基金项目(2016CFB147) 黄冈师范学院化学实验教学示范中心项目(zj201722 zj201723)
关键词 碱土金属配合物 配位聚合物 锶配合物 alkaline-earth metals complex coordination polymer strontium complex
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  • 1Harder, S. Intramolecular C-H activation in alkaline-earth metal complexes. Ange. Chem. Int. Ed. 2003, 42, 3430–3434.
  • 2Westerhausen, M.; Schneiderbauer, S.; Kneifel, A. N.; Sotl, Y.; Mayer, P.; Noth, H.; Zhong, Z.; Dijkstra, P. J.; Feijen, J. Organocalcium compounds with catalytic activity for the ring-opening polymerization of lactones. Eur. J. Inorg. Chem. 2003, 3432–3439.
  • 3Kobayashi, S.; Yamashita, Y. Alkaline earth metal catalysts for asymmetric reactions. Acc. Chem. Res. 2011, 44, 58–71.
  • 4Fromm. K. M. Recent advances in tailoring the aggregation of heavier alkaline earth metal halides, alkoxides and aryloxides from non-aqueous solvents. J. Chem. Soc., Dalton Trans. 2006, 5103–5112.
  • 5Fromm, K. M.; Gueneau, E. D.; Bernerdinelli, G.; Goesmann, H.; Weber, J.; Mayor-López, M. J.; Boulet, P.; Chermette, H. Understanding the formation of new clusters of alkali and alkaline earth metals: a new synthetic approach, single-crystal structures, and theoretical calculations. J. Am. Chem. Soc. 2003, 125, 3593–3604.
  • 6Zhang, X. F.; Deng, Z. P.; Huo, L. H.; Feng, Q. M.; Gao, S. Four alkali-induced 3D strontium(II) coordination polymers constructed from imidazole-4,5-dicarboxylate: syntheses, crystal structures, and properties. Eur. J. Inorg. Chem. 2012, 5506–5514.
  • 7Fromm, K. M. Coordination polymer networks with s-block metal ions. Coord. Chem. Rev. 2008, 252, 856–885.
  • 8Wang, X. L.; Qin, C.; Wang, E. B.; Li, Y. G.; Su, Z. M.; Xu, L.; Carlucci, L. Entangled coordination networks with inherent features of polycatenation, polythreading, and polyknotting. Angew. Chem. Int. Ed.2005, 44, 5824–5827.
  • 9Forster, P. M.; Burbank, A. R.; Livage, C.; Ferey, G.; Cheetham. A. K. The role of temperature in the synthesis of hybrid inorganic-organic materials: the example of cobalt succinates. Chem. Commun.2004, 368–369.
  • 10Tong, M. L.; Kitagawa, S.; Chang, H. C.; Ohba, M. Temperature-controlled hydrothermal synthesis of a 2D ferromagnetic coordination bilayered polymer and a novel 3D network with inorganic Co3(OH)2 ferrimagnetic chains. Chem. Commun. 2004, 418–419.

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