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Robust self-supported anode by integrating Sb2S3 nanoparticles with S,N-codoped graphene to enhance K-storage performance 被引量:12

Robust self-supported anode by integrating Sb_2S_3 nanoparticles with S,N-codoped graphene to enhance K-storage performance
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摘要 Developing high-performance anode materials for potassium-ion batteries is significantly urgent. We here demonstrate Sb_2S_3 nanoparticles(~20 nm) homogeneously dispersed in porous S,N-codoped graphene framework(Sb_2S_3-SNG) as a self-supported anode material for potassium-ion batteries. The rational structure design of integrating Sb_2S_3 nanoparticles with S,N-codoped graphene contributes to high reactivity, strong affinity, good electric conductivity, and robust stability of the composite, enabling superior K-storage performance. Moreover, the self-supported architecture significantly decreases the inactive weight of the battery, resulting in a high energy density of a Sb_2S_3-SNG/KVPO_4 F-C full cell to ~166.3 W h kg^(-1). Developing high-performance anode materials for potassium-ion batteries is significantly urgent. We here demonstrate Sb2S3 nanoparticles (-20 nm) homogeneously dispersed in porous S,N-codoped graphene framework (Sb2S3-SNG) as a self-supported anode material for potassium-ion batteries. The rational structure design of integrating Sb2S3 nanoparticles with S,N-codoped graphene contributes to high reactivity, strong affinity, good electric conductivity, and robust stability of the composite, enabling superior K-storage performance. Moreover, the self-supported architecture significantly decreases the inactive weight of the battery, resulting in a high energy density ofa Sb2S3-SNG/KVPO4F-C full cell to -166.3 W h kg- 1.
出处 《Science China Chemistry》 SCIE EI CAS CSCD 2017年第12期1533-1539,共7页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China (21231005, 51231003) the Program of Introducing Talents of Discipline to Universities of China (B12015)
关键词 Sb2S3 nanoparticles S N-codoping self-supported graphene foam anode potassium-ion batteries Sb2S3 nanoparticles, S,N-codoping, self-supported graphene foam, anode, potassium-ion batteries
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