环氧化物与CO_2环加成反应高效催化剂研究进展

Research progress of high efficiency catalysts for cycloaddition of epoxides with CO_2

从催化剂的种类、特点、设计思路以及存在的优缺点等方面,概述了这类环加成反应所需的高效催化剂,包括过渡金属配合物、离子液体、有机碱、金属氧化物、负载型催化剂等。最后对设计、开发高效环氧化物与CO_2环加成反应催化剂提出设想和展望。

The cycloaddition reaction of CO2 with epoxide is one of the most promising subjects for CO2 fixation.This paper summarizes the high efficiency catalysts needed by the cycloaddition reaction,including transition metal complexes,ionic liquids,organic bases,metal oxides,supported catalysts,and so on. The variety,characteristics,design ideas and advantages and disadvantages of these catalysts are analyzed. The ideas and prospects to design and develop high efficient catalyst for the cycloaddition reaction between CO2 and epoxides are proposed.