摘要
通过结合静电纺丝和氨化技术方法合成了Eu^(2+)掺杂的GaN(GaN:Eu^(2+))纳米纤维.SEM和TEM图像显示纳米纤维由尺寸均匀分布的GaN纳米颗粒组成.XRD测试结果表明,GaN:Eu^(2+)样品主要为六方相GaN(hGaN),其平均粒径为7.3 nm.进一步的拉曼测试结果显示出现了两个额外的GaN拉曼位移,波数分别位于252和422 cm^(-1).室温光致发光谱表明GaN基质中的Eu^(2+)在407
Eu^2+-doped GaN(GaN: Eu^2+) nanofibers were synthesized by a facile approach that combined electrospinning and ammonification techniques. SEM and TEM images revealed that the nanofibers consist of GaN nanoparticles with uniform size. XRD result showed that the GaN: Eu^2+ sample predominantly exhibited the hexagonal phase of GaN(h-GaN) and the average grain size was evaluated to be 7. 3 nm. Further Raman characterization showed that two extra GaN Raman shifts with the peaks of 252 and 422 cm^-1 were observed. As was expected,characteristic strong blue emission from Eu^2+ ions doped in GaN matrix was observed at 407 nm in the photoluminescence spectrum.
出处
《红外与毫米波学报》
SCIE
EI
CAS
CSCD
北大核心
2017年第6期646-649,共4页
Journal of Infrared and Millimeter Waves
基金
Supported by National Natural Science Foundation of China(11574301,61274008,61674147,11404239)
the Opening Project of Guangxi Key Laboratory of Precision Navigation Technology and Application
the National Science Foundation for Post-doctoral Scientists of China(2016M600231)
National Natural Sciences Foundation of Tianjin(14JCQNJC01000)