摘要
铁催化的有机金属亲核试剂与有机卤化物亲电试剂参与的偶联反应是目前形成新的碳碳键的最有效方法之一.综述了最近10年来铁催化的格式试剂参与的偶联反应中有关添加物的相关效应及其影响.
Iron-catalyzed cross-coupling reactions between organometallic nucleophiles and organic halides as electrophiles represent one of the most powerful methods in the field of carbon-carbon bond construction. This review is concerned with the additive effect in iron-catalyzed cross-coupling reactions of Grignard reagents, whose results were published in recent years.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2018年第1期40-50,共11页
Chinese Journal of Organic Chemistry
基金
supported by the National Natural Science Foundation of China(No.21672181/21272199)
the Shenzhen Science and Technology Innovation Committee(No.JCYJ20160608151520697)
the National Natural Science Foundation of China and the Research Grants Council of Hong Kong,SAR(RGC)Joint Research Scheme(No.N_CUHK451/13)
the RGC(Nos.403012/CUHK14309216/CUHK14303815,Poly U C5023-14G)
the State Key Laboratory of Synthetic Chemistry and GHP/004/16GD from Innovation and Technology Commission~~
关键词
铁催化
偶联反应
格式试剂
添加物效应
iron-catalyzed
cross-coupling
Grignard reagents
additive effect
