α-亚胺基磷杂二茂铁的合成、结构及配位化学研究（英文）

Synthesis, Structure and Coordination Chemistry of an α-Iminophosphaferrocene

3,4-二甲基-1-苯基磷杂环戊二烯通过两次[1,5]σ-迁移在α-位分别引入苯基和亚胺基得到α-亚胺基磷杂环戊二烯负离子1,1和[Cp~*FeCl]_n反应得到新的P,N双齿配体α-亚胺基磷杂二茂铁2.2可以和Mo和Rh等形成配合物,其中2及其Mo配合物的结构由X射线单晶衍射确定.

An 2-iminophospholide 1 can be obtained via two [1,5] shifts by reaction of potassium tert-butoxide with 3,4-dimethyl-1-phenylphosphole and an imidoyl chloride. The reaction of 1 with [Cp-＊FeCl]_n affords a 2-iminophosphaferrocene 2 which behaves as a P,N chelating ligand toward Mo（CO）_4 and Rh（CO）_2]-＋. The X-ray crystal structures of 2 and its Mo complex have been recorded