氢分子离子结构参数的研究

Study on Structure Parameters of Hydrogen Molecular Ion

从氢分子转化为氢分子离子动态平衡的微观过程出发,采用库仑吸引力和排斥力平衡、库仑相互作用势能守恒理论,建立了氢分子离子的结构模型,归纳出氢分子离子的平衡核间距、离子键能、振动力常数的计算方程,根据该方程计算了氢分子离子的键长、键能、振动力常数。结果表明,归纳的氢分子离子的结构模型参数方程式简单、易操作,且计算的理论值与实验值高精度吻合。

from the dynamic equilibrium of hydrogen molecules to the microscopic process of dynamic equilibrium of hydrogen molecules, the parameters of hydrogen molecular ion are calculated by the idea of Coulomb attraction force, repulsive force balance, and the conservation of potential energy of Coulomb interaction. A very simple and accurate method for calculating the ionic bond length, bond energy and vibration force constant of hydrogen molecules is proposed. Three formulas without any artificial parameters are deduced. The theoretical values of all the parameters are in good agreement with the experimental values.