绿色催化体系合成己二酸的适用性研究

Applicability research on synthesis of adipic acid by green catalytic system

绿色化学的主要原则之一是在合成方法中采用高活性的催化剂,催化剂具有较广的适用范围。着重讨论了钨酸钠、磷钨酸及三氧化钨3种催化体系的适用性,分别研究了每种催化剂对环己烯、环己醇和环己酮的催化作用,寻找适用性较好的高活性催化剂。

One of the main principles of green chemistry is the high activity of the catalyst in synthesis process,and catalyst has wide application range.This paper focuses on catalytic system application of sodium tungstate,phosphotungstic acid and tungsten trioxide,studies catalytic effects of each catalyst on cyclohexene,cyclohexanol and cyclohexanone to find highly active catalysts with good applicability.