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REACH compliant epoxides used in the synthesis of Fe(Ⅲ)-based aerogel monoliths for target fabrication

REACH compliant epoxides used in the synthesis of Fe(Ⅲ)-based aerogel monoliths for target fabrication
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摘要 Aerogel materials manufactured from metal oxides have been used as components in numerous high-energy density physics targets. These aerogels have been identified to be used as a future target material in the AWE fielded campaigns at the US National Ignition Facility. A wide variety of metal oxide aerogels are required for future campaigns and therefore a versatile manufacturing route is sought; as such, an epoxide-assisted sol–gel route was investigated. Under the European Union Registration, Evaluation, Authorization and Restriction of Chemicals legislation, the most commonly used epoxide, propylene oxide, is recognized as a substance of very high concern(SVHC). This work sought to investigate suitable alternative epoxides for use in target manufacture. The outcome was the identification of synthesis routes for stable metal oxide aerogel monoliths using epoxides not subject to the above restrictions. Aerogel materials manufactured from metal oxides have been used as components in numerous high-energy density physics targets. These aerogels have been identified to be used as a future target material in the AWE fielded campaigns at the US National Ignition Facility. A wide variety of metal oxide aerogels are required for future campaigns and therefore a versatile manufacturing route is sought; as such, an epoxide-assisted sol-gel route was investigated. Under the European Union Registration, Evaluation, Authorization and Restriction of Chemicals legislation, the most commonly used epoxide, propylene oxide, is recognized as a substance of very high concern (SVHC). This work sought to investigate suitable alternative epoxides for use in target manufacture. The outcome was the identification of synthesis routes for stable metal oxide aerogel monoliths using epoxides not subject to the above restrictions.
出处 《High Power Laser Science and Engineering》 SCIE CAS CSCD 2017年第4期8-13,共6页 高功率激光科学与工程(英文版)
基金 funded by AWE,Aldermaston,Reading,Berkshire,RG7 4PR,UK
关键词 AEROGEL EPOXIDE metal oxide sol–gel SVHC aerogel epoxide metal oxide sol-gel SVHC
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