烧结烟气氨法联合活性炭协同脱硫脱硝

Desulfurization and denitration of sintering flue gas based on ammonia and activated carbon process

为实现铁矿烧结烟气SO_2和NO_x协同减排,采用氨法联合活性炭对烧结烟气进行协同脱硫脱硝研究。结果表明,在经氨法预先脱除SO_2后,仅凭活性炭单级吸附就能获得70%以上的脱硝率。氨法联合活性炭法脱硝的机理是由于逃逸的NH_3与活性炭表面的C-OH官能团结构发生化学吸附反应,最终生成了N_2和H_2O。针对目前已有氨法脱硫装置的烧结厂而言,只需在脱硫喷淋塔后直接连接单级活性炭吸附塔,即可达到99%以上的脱硫率和70%以上的脱硝率,不仅可大幅降低设备投资成本,还可解决氨的逃逸和二次环境污染的问题。

In order to reduce the emission of SO2 and NOx in the iron ore sintering,the desulfurization and denitration of iron ore sintering flue gas based on ammonia-activated carbon process was developed. The results show that more than 70% denitration rate was obtained using activated carbon after SO2 was removed by ammonia process. The denitration mechanism is that the escaping NH3 reacted with C-OH in the surface of activated carbon to produce the N2 and H2O. For the sintering plants using ammonia desulfurization process,more than 99% desulfurization rate and 70% denitration rate were achieved just connecting a single stage activated carbon adsorption tower after the desulfurization spray tower,which could reduce the capital cost and also solve the secondary environmental pollution due to the NH3 escape.