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Crystal and Molecular Structure of(η_(5)-C_(5)H_(5))_(2)Yb(NC_(4)H_(4))(OC_(4)H_(8))

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摘要 The complex(C<sub>5</sub>H<sub>5</sub>)2 Yb(NC4H4)(OC<sub>4</sub>H<sub>8</sub>) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule has crystallographic mirror symmetry.The Yb(Ⅲ) has a distorted tetrahedral coordination geometry. The complex(C<sub>5</sub>H<sub>5</sub>)2 Yb(NC4H4)(OC<sub>4</sub>H<sub>8</sub>) crystallizes in orthorhombic system with space group Pnma and a=15.552(4),b=12.491(3),c=8. 711(3),V=1692. 2(7),Z=4 and Dc=1.733 g/cm3. Crystal study has shown that the molecule has crystallographic mirror symmetry.The Yb(Ⅲ) has a distorted tetrahedral coordination geometry.
出处 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 1994年第5期346-349,共页 结构化学(英文)
关键词 crystal structure LANTHANIDE pyrrolyl complex crystal structure lanthanide pyrrolyl complex
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