摘要
ＳｔｒｕｃｔｕｒｅｏｆＭｏｌｙｂｄｅｎｕｍＣｏｍｐｌｅｘｏｆＢｅｎｚｏｔｈｉａｚｏｌｅ－２－ｔｈｉｏｌａｔｅ（η<sup>５</sup>－Ｃ<sub>５</sub>Ｈ<sub>５</sub>）Ｍｏ（ＣＯ）<sub>２</sub>（Ｃ<sub>７</sub>Ｈ<sub>４</sub>ＮＳ<sub>２</sub>）ＣｈｅｎｇＧｕｏ－Ｂａｏ<sup>ａ</sup>；ＷｕＱｉａｎｇ－Ｊｉｎ<sup>ｂ</sup>；ＨｕａｎｇＸｉａｏ－Ｙｉｎｇ<sup>.</sup>..
C<sub>14</sub>H<sub>9</sub>NO<sub>2</sub>S<sub>2</sub>Mo,Mr=383.29,triclinic,space group P1,a=11.658（4）,b=16.218（8）,c=7.895（3）,a=97.58（4）,β=106.04（3）,γ=85.62（3）°,V=1421（2）,Z=4,D<sub>c</sub>=1.79 g/cm￣3,μ=11.81 cm￣（-1）.F（000）=760.Refinement converged to R=0.049 and Rω=0.058 for 3153 independent observed reflections.The compound is a mononuclear molybdenum complex containing benzothiazole-2-thiolato ligand.The molybdenum atom is coordinated by the two carbonyl carbon atoms,tlie cyclopentadienyl carbon atoms,and the nitrogen atom and sulfur atom of benzothiazole-2-thiolate.The coordination polyhedron may be described as a trapezoidal pyramid with the Cp ring centroid as a top.
