摘要
ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ２－Ｔｈｉｏ－２－（３＇－ｍｅｔｈｙｌ－４＇－ｃｈｌｏｒｏ－ｏｘｙｐｈｅｎｙｌ）－１，３，２－ｂｅｎｚｏｄｉｏｘａｐｈｏｓｐｈｏｌｅＳｕｎＭｉｎｇ；ＬｉｕＸｉａｏ－Ｌａｎ；ＭｉａｏＦａｎｇ－Ｍｉｎｇ（Ｉｎｓｔｉｉｔ...
C13H10ClO3PS,Mr = 312.71,monoclinic,space group P21/a,a=8.762 (5).b=11.733(4),c=13.310(4) A,β=98,28(4)°,V=1354(1) A3, Z=4, Dx=l.53g/cm3,μ=49.82 cm-1,F(000)=640,R=0.053,Rω=0.055.The endocyclic O-P-O bond angle in this compound is 97.5(2)°,and all atoms in the phenyl ring and the five-membered ring of benzodioxaphosphole moiety in the molecule are essentially coplanar with a maximum deviation of 0.065 A.
