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Synthesis and red electroluminescence of a dimesityl-functionalized bistetracene

Synthesis and red electroluminescence of a dimesityl-functionalized bistetracene
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摘要 A novel dimesityl-decorated bistetracene derivative 8,16-dimesityltetraceno[2,1,12,11-opqra]tetracene(DMTA) has been synthesized and characterized. Its single crystal analysis demonstrates that the parent bistetracene backbone is almost in a plane without any intermolecular 7 r-stacking interaction. DMTA exhibited the low-energy absorption at 560/607 nm and emission spectra at 617/663 nm, respectively.The fabricated device based on DMTA doping into 2,6-bis(3-(9 H-carbazol-9-yl)phenyl)pyridine(1 %) as an emitter present a maximum brightness of 632 cd/m^2 at 14.7 V with the CIE coordinate of(0.623,0.349). A novel dimesityl-decorated bistetracene derivative 8,16-dimesityltetraceno[2,1,12,11-opqra]tetracene(DMTA) has been synthesized and characterized. Its single crystal analysis demonstrates that the parent bistetracene backbone is almost in a plane without any intermolecular 7 r-stacking interaction. DMTA exhibited the low-energy absorption at 560/607 nm and emission spectra at 617/663 nm, respectively.The fabricated device based on DMTA doping into 2,6-bis(3-(9 H-carbazol-9-yl)phenyl)pyridine(1 %) as an emitter present a maximum brightness of 632 cd/m^2 at 14.7 V with the CIE coordinate of(0.623,0.349).
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2018年第2期293-296,共4页 中国化学快报(英文版)
基金 financially supported by the National Natural Science Foundation of China(Nos. 21102031, 21442010 and 21672051) the Natural Science Foundation of Hebei Province for Distinguished Young Scholar(No. B2017201072) Cultivation Project (No. B2015201183) the Natural Science Foundation of Hebei University (No. 2015JQY02)
关键词 Synthesis Polycyclic aromatic hydrocarbons Single crystal Photophysical property Electroluminescence Synthesis Polycyclic aromatic hydrocarbons Single crystal Photophysical property Electroluminescence
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