摘要
NiMnO3 perovskite catalysts supported on cordierite modified by CexZr（1-x）O2 coatings were prepared using impregnation and sol-gel methods for catalytic combustion of single/double component VOCs at different concentrations and GHSV of 15,000 h^（-1）, which were characterized by BET, XRD, SEM, FT-IR, H2-TPR and O2-TPD. After coating modification, the specific surface area of catalysts is improved obviously.Among the catalysts, the Ce（0.75）Zr（0.25）O2 coating modified NiMnO3 catalyst exhibits the best catalytic activity for VOCs combustion with 95.6% conversion at 275 ℃ and has stable activity when catalyst is embalmed at 800 ℃. In addition, the catalyst also presents the excellent water-resistant and conversion stability over time-on-stream condition. The reason is that Ce（0.75）Zr（0.25）O2 coating can promote more lattice distortion and defects and smaller crystal size, which improve oxygen transfer capability and dispersion of active component.
NiMnO3 perovskite catalysts supported on cordierite modified by CexZr（1-x）O2 coatings were prepared using impregnation and sol-gel methods for catalytic combustion of single/double component VOCs at different concentrations and GHSV of 15,000 h^（-1）, which were characterized by BET, XRD, SEM, FT-IR, H2-TPR and O2-TPD. After coating modification, the specific surface area of catalysts is improved obviously.Among the catalysts, the Ce（0.75）Zr（0.25）O2 coating modified NiMnO3 catalyst exhibits the best catalytic activity for VOCs combustion with 95.6% conversion at 275 ℃ and has stable activity when catalyst is embalmed at 800 ℃. In addition, the catalyst also presents the excellent water-resistant and conversion stability over time-on-stream condition. The reason is that Ce（0.75）Zr（0.25）O2 coating can promote more lattice distortion and defects and smaller crystal size, which improve oxygen transfer capability and dispersion of active component.
基金
Project supported by the Science and Technology Department of Jiangsu Province(BE2016769)
the Natural Science Foundation of China(51172107)
Natural Science Foundation of the Jiangsu Higher Education Institutions of China(14KJB430014)
Open fund by Jiangsu Engineering Technology Research Center of Environmental Cleaning Materials(KFK1503)
the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
