摘要
在水溶剂中,采用水热法合成了含氮配体化合物[H_2(phen)_2·C_6H_5S_2O_6N]·2H_2O(phen=1,10-邻菲罗啉)。采用X射线单晶衍射和元素分析等方法对其进行了表征。X射线单晶衍射表征结果表明,该配合物晶体属于三斜晶系。研究了该化合物的紫外可见光谱以及热稳定性。该化合物紫外可见光谱的峰在315nm,热稳定性良好。
In aqueous solvent,the compound of [H_2（phen）_2·C_6H_5S_2O_6N]·2H_2O（phen=1,10-phenanthroline） containing N-donor ligand was synthesized by hydrothermal method.The X-ray single crystal diffraction and elemental analysis were used to characterize the compound.And the results showed that the compound belonged to the triclinic system.The UV-Vis spectrum and thermal stability of the compound were also investigated.The peak of the UV-vis spectrum of the compound was at 315 nm.And it had a good thermal stability.
作者
张力嫱
闫启博
王莹
张娜
张宇航
关磊
任冰洁
ZHANG Li-qiang;YAN Qi-bo;WANG Ying;ZHANG Na;ZHANG Yu-hang;GUAN Lei;REN Bing-jie(College of Chemistry, Chemical Engineering and Environment Engineering, Liaoning University of Petroleum and Chemical Engineering, Fushun 113001, China;Department of Chemical Engineering, Fushun Vocational Technology Institute, Fushun 113122, China)
出处
《化学与粘合》
CAS
2018年第2期113-115,共3页
Chemistry and Adhesion
基金
校创新创业训练项目(编号:201710148000118
201710148000147)
关键词
化合物
合成
配体
Compound
synthesis
ligand
