摘要
A Pd-catalyzed multi-component carbonylative difluoroalkylation/perfluoroalkylation through the alkyne difunctionalization process has been developed. Besides, new functional fluoropolymer materials have been successfully synthesized. Owing to the presence of the fluorine element, the materials present excellent chemical resistance, high-temperature-resistance and outstanding hydrophobicity simultaneously, which may significantly make them great appealing in the industrial production and life science as well.
A Pd-catalyzed multi-component carbonylative difluoroalkylation/perfluoroalkylation through the alkyne difunctionalization process has been developed. Besides, new functional fluoropolymer materials have been successfully synthesized. Owing to the presence of the fluorine element, the materials present excellent chemical resistance, high-temperature-resistance and outstanding hydrophobicity simultaneously, which may significantly make them great appealing in the industrial production and life science as well.
基金
Acknowledgement China We thank the National Natural Science Foundation of （NSF 21472073 and 21532001）, and the ＂111＂ Project.
