摘要
选取叔丁基邻苯二酚和[Cu_2(dppm)_2(C_7H_7N)(μ-NO_3)](NO_3)为催化剂,丙烯类化合物和混合碳五为原料合成降冰片烯衍生物。研究表明,在-15℃~5℃温度下,混合碳五中的环戊二烯和丙烯类化合物经Diels-Alder反应得到目标产物,收率可达74.1%~87.8%。
In this paper,acrylic compounds and C5 were adopted as raw materials,and tert-butyl catechol and[Cu2（ dppm）2（ C7H7 N）（ μ-NO3） ]（NO3） were selected as catalysts to synthesis norbornene and its derivates. Experimental research have shown that the target products were obtained through the Diels-Alder reaction between cyclopentadiene in C5 and acrylic compounds with 74. 1% - 87. 8% yield at the temperature of-15℃ - 5℃.
作者
孙敏青
马欣
屈凤波
杨振强
陈辉
张银龙
SUN Min-qing;MA Xin;QU Feng-bo;YANG Zhen-qiang;CHEN Hui;ZHANG Yin-long(Institute of Chemistry Henan Academy of Sciences, Zhengzhou 450002, Henan, China;Henan Kingorgchem Chemical Technology Co., Ltd., Zhengzhou 450002, Henan, China)
出处
《合成材料老化与应用》
2018年第1期48-50,共3页
Synthetic Materials Aging and Application
基金
河南省科技创新杰出青年基金(174100510018)
河南省科技开放项目(17210600063)
