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Helium ion irradiation effects on neodymium and cerium co-doped Gd_2Zr_2O_7 pyrochlore ceramic 被引量:1

Helium ion irradiation effects on neodymium and cerium co-doped Gd_2Zr_2O_7 pyrochlore ceramic
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摘要 This paper studies the helium ions irradiation effects on Nd and Ce co-doped Gd_2 Zr_2 O_7 ceramics. where Nd replaces the Gd site and Ce replaces the Zr site respectively. A series of(Gd_(1-x)Nd_x)_2(Zr_(1-y)Ce_y)_2 O_7(0 ≤ x, y ≤ 1) ceramics were irradiated with a 500 keV He ions at room temperature at fluences ranging from 1 × 10^(15) to 1 × 10^(17) ions/cm^2. The irradiated samples were characterized using GIXRD, Raman and SEM measurements. From the GIXRD and Raman observations, the results indicate that all the samples display a deficient fluorite structure after irradiation. The irradiation toleration increases with the irradiation depth increasing under experimental conditions, and Nd_2 Ce_2 O_7 has the best irradiation stability in the(Gd_(1-x)Nd_x)_2(Zr_(1-y)Ce_y)_2 O_7(0≤ x. y≤1). Based on SEM results, the irradiated samples are still relatively dense and uniform, and no second phase exists. This paper studies the helium ions irradiation effects on Nd and Ce co-doped Gd_2 Zr_2 O_7 ceramics. where Nd replaces the Gd site and Ce replaces the Zr site respectively. A series of(Gd_(1-x)Nd_x)_2(Zr_(1-y)Ce_y)_2 O_7(0 ≤ x, y ≤ 1) ceramics were irradiated with a 500 keV He ions at room temperature at fluences ranging from 1 × 10^(15) to 1 × 10^(17) ions/cm^2. The irradiated samples were characterized using GIXRD, Raman and SEM measurements. From the GIXRD and Raman observations, the results indicate that all the samples display a deficient fluorite structure after irradiation. The irradiation toleration increases with the irradiation depth increasing under experimental conditions, and Nd_2 Ce_2 O_7 has the best irradiation stability in the(Gd_(1-x)Nd_x)_2(Zr_(1-y)Ce_y)_2 O_7(0≤ x. y≤1). Based on SEM results, the irradiated samples are still relatively dense and uniform, and no second phase exists.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2018年第4期398-403,共6页 稀土学报(英文版)
基金 Project supported by the National Natural Science Foundation of China(21507105,51574201) Ministry of Housing and Urban-Rural Development(2014-K3-037) Sichuan Science and Technology Innovation Talent Project(2016119) Scientific and Technical Youth Innovation Group(Southwest Petroleum University)(2015CXTD05)
关键词 Helium ion irradiation Ceramic Pyrochlore Co-doping Rare earths Helium ion irradiation Ceramic Pyrochlore Co-doping Rare earths
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