摘要
An attractive way to prepare W/TaC based cermet at a relatively low temperature was proposed and confirmed experimentally. The thermodynamics calculations indicated that the reaction between WC and Ta2O5was feasible at as low a temperature as 1 400 ℃. The experimental results showed that W/TaC cermet could be fabricated by in-situ reaction sintering process at 1400 ℃ for 2 h in vacuum. The open porosity and bulk density of the W/TaC cermet were 15.3% and 13.4 g/cm3. Further, the microstructural features revealed that W, TaC, and Ta2WO8were identified to be the main constituents of the W/TaC cermet. The mass lose rate and linear recession rate of the W/TaC cermet during an oxyacetylene torch test were 0.0048 g/s and 0.0233 mm/s, respectively. The high porosity, the presence of Ta2WO8phases within W/TaC and evaporation of WO3on the surface of the composite contributed to the decrease of ablative property when comparing with pure W.
An attractive way to prepare W/TaC based cermet at a relatively low temperature was proposed and confirmed experimentally. The thermodynamics calculations indicated that the reaction between WC and Ta_2O_5 was feasible at as low a temperature as 1 400 ℃. The experimental results showed that W/TaC cermet could be fabricated by in-situ reaction sintering process at 1400 ℃ for 2 h in vacuum. The open porosity and bulk density of the W/TaC cermet were 15.3% and 13.4 g/cm^3. Further, the microstructural features revealed that W, TaC, and Ta_2WO_8 were identified to be the main constituents of the W/TaC cermet. The mass lose rate and linear recession rate of the W/TaC cermet during an oxyacetylene torch test were 0.0048 g/s and 0.0233 mm/s, respectively. The high porosity, the presence of Ta_2WO_8 phases within W/TaC and evaporation of WO_3 on the surface of the composite contributed to the decrease of ablative property when comparing with pure W.
基金
Funded by the Aid Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province
the Aid Program for Innovative Research Team in National University of Defense Technology
