摘要
Effective heat dissipation is a crucial issue in electrochemical energy storage devices. Thus, it is highly desirable to develop high-performance electrode materials with high thermal conductivity. Here, we report a facile one-step electrodeposition method to synthesize ternary cobalt nickel sulfide（CoNi2S4）flower-like nanosheets which are grown on graphite foil（GF） as binder-free electrode materials for supercapacitors. The as-fabricated GF/CoNi2S4 integrated electrode manifested an excellent thermal conductivity of 620.1 W·m-1·K-1 and a high specific capacitance of 881 F·g-2 at 5 mA cm-2, as well as good rate capability and cycling stability. Ultimately, the all-solid-state symmetric supercapacitor based on these advanced electrodes demonstrated superior heat dissipation performance during the galvanostatic charge-discharge processes. This novel strategy provides a new example of effective thermal management for potential applications in energy storage devices.
Effective heat dissipation is a crucial issue in electrochemical energy storage devices. Thus, it is highly desirable to develop high-performance electrode materials with high thermal conductivity. Here, we report a facile one-step electrodeposition method to synthesize ternary cobalt nickel sulfide（CoNi2S4）flower-like nanosheets which are grown on graphite foil（GF） as binder-free electrode materials for supercapacitors. The as-fabricated GF/CoNi2S4 integrated electrode manifested an excellent thermal conductivity of 620.1 W·m-1·K-1 and a high specific capacitance of 881 F·g-2 at 5 mA cm-2, as well as good rate capability and cycling stability. Ultimately, the all-solid-state symmetric supercapacitor based on these advanced electrodes demonstrated superior heat dissipation performance during the galvanostatic charge-discharge processes. This novel strategy provides a new example of effective thermal management for potential applications in energy storage devices.
基金
financially supported by the National Natural Science Foundation of China (21203236)
Shenzhen Peacock Plan (KQCX2015033117354154)
Shenzhen basic research plan (JCYJ2015052114432090)
the Science & Technology Project of Educational Commission of Jiangxi Province, China (GJJ161198)
