摘要
Surface engineering is an effective strategy to restrain the generation of rocksalt NiO phase on surface of layered LiNi0.815Co0.15Al0.035O2(NCA) primary nanoparticles, a representative Ni-rich layered oxides cathode materials. Herein, we demonstrate the kilogram-scale synthesis of few-layer reduced graphene oxide(rGO) conformably coated NCA primary nanoparticles cathode materials by a mechanical wet ball-milling strategy. The lightening rGO coating layer effectively avoids the direct contact of electrolyte and NCA with rapid electrons transfer. As a result, the as-obtained NCA@rGO hybrids with only 1.0 wt% rGO content can deliver a high specific capacity(196 mAh g-1 at 0.2 C) and fast charge/discharge capability(127 mAh g-1 at 5 C), which is much higher than the corresponding NCA nanoparticles(95 mAh g-1 at 5 C). Even after100 cycles at 1 C, 91.7% of initial reversible capacity is still maintained. Furthermore, a prismatic pouch cell(240 mAh) is also successfully assembled with the commercial graphite anode.
Surface engineering is an effective strategy to restrain the generation of rocksalt NiO phase on surface of layered LiNi0.815Co0.15Al0.035O2(NCA) primary nanoparticles, a representative Ni-rich layered oxides cathode materials. Herein, we demonstrate the kilogram-scale synthesis of few-layer reduced graphene oxide(rGO) conformably coated NCA primary nanoparticles cathode materials by a mechanical wet ball-milling strategy. The lightening rGO coating layer effectively avoids the direct contact of electrolyte and NCA with rapid electrons transfer. As a result, the as-obtained NCA@rGO hybrids with only 1.0 wt% rGO content can deliver a high specific capacity(196 mAh g-1 at 0.2 C) and fast charge/discharge capability(127 mAh g-1 at 5 C), which is much higher than the corresponding NCA nanoparticles(95 mAh g-1 at 5 C). Even after100 cycles at 1 C, 91.7% of initial reversible capacity is still maintained. Furthermore, a prismatic pouch cell(240 mAh) is also successfully assembled with the commercial graphite anode.
基金
supported by the National Natural Science Foundation of China (21522602, 51672082, 91534202, and 91534122)
Shanghai Rising-Star Program (15QA1401200)
the Program for Shanghai Youth Top-notch Talent
the Fundamental Research Funds for the Central Universities (222201718002)