摘要
A series of Ln（Ⅲ） dipivaloylmethanates Ln（dpm）3 has been obtained. The crystalstructures of Tm（dpm）3 （1） and Yb（dpm）3 （2） were determined by X-ray analysis at 200（2） K（Pmn2b Z = 2; a = 17.7509（8）, b = 10.5805（4）, c = 9.8380（4） A, V = 1847.7（1） A3 for （1） and a =17.7272（6）, b = 10.5882（3）, c = 9.8440（3） A, V= 1847.7（1） A^3 for （2））. These data complete thestructural evaluation of lanthanoid tris-dipivaloylmethanates. Compounds 1 and 2 are isostructuralto the complexes Ln（dpm）3 （Ln -- Er and Lu）. It is demonstrated that the volatility of tris-dipivaloylmethanates of rare earth elements increases from the complex of Lu to that of La.
A series of Ln（Ⅲ） dipivaloylmethanates Ln（dpm）3 has been obtained. The crystalstructures of Tm（dpm）3 （1） and Yb（dpm）3 （2） were determined by X-ray analysis at 200（2） K（Pmn2b Z = 2; a = 17.7509（8）, b = 10.5805（4）, c = 9.8380（4） A, V = 1847.7（1） A3 for （1） and a =17.7272（6）, b = 10.5882（3）, c = 9.8440（3） A, V= 1847.7（1） A^3 for （2））. These data complete thestructural evaluation of lanthanoid tris-dipivaloylmethanates. Compounds 1 and 2 are isostructuralto the complexes Ln（dpm）3 （Ln -- Er and Lu）. It is demonstrated that the volatility of tris-dipivaloylmethanates of rare earth elements increases from the complex of Lu to that of La.
基金
Funded by the National Scholarship Fund
