摘要
Photochemical reduction of CO2 with H20 into energy-rich chemicals using inexhaustible solar energy is an appealing strategy to simultaneously address the global energy and environmental issues. Earth-abundant metal complexes show promising application in this field due to their easy availability, rich redox valence and tunable property. Great progress has been seen on catalytic reduction of CO2 under visible light illumination employing earth-abundant metal complexes and their hybrids as key contributors, especially for producing CO and HCOOH via the two-electron reduction process. In this minireview, we will summarize and update advances on earth-abundant metal complex-derived photocatalytic system for visible-light driven CO2 photoreduction over the last 5 years. Homogeneous earth-abundant metal complex photocatalysts and earth-abundant metal complex derived hybrid photocatalysts were both presented with focus on efficient improvement strategy.
Photochemical reduction of CO2 with H20 into energy-rich chemicals using inexhaustible solar energy is an appealing strategy to simultaneously address the global energy and environmental issues. Earth-abundant metal complexes show promising application in this field due to their easy availability, rich redox valence and tunable property. Great progress has been seen on catalytic reduction of CO2 under visible light illumination employing earth-abundant metal complexes and their hybrids as key contributors, especially for producing CO and HCOOH via the two-electron reduction process. In this minireview, we will summarize and update advances on earth-abundant metal complex-derived photocatalytic system for visible-light driven CO2 photoreduction over the last 5 years. Homogeneous earth-abundant metal complex photocatalysts and earth-abundant metal complex derived hybrid photocatalysts were both presented with focus on efficient improvement strategy.
