摘要
Carbon dioxide is a sufficient and important carbon resource, which has been widely used as a C1 building block in synthetic chemistry. Car- bonylations with CO are important processes in industry. However, due to the toxicity of CO, its storage and transport are problematic. Attentions are gradually focused on using other safe reagents to be the CO surrogates in carbonylation reactions. This review focuses on the summary of recent devel- opments in using CO_2 as a CO surrogate in homogeneous catalysis. Reductive processes by using H2, Si-H, alcohols, etc and redox-neutral processes are separately summarized.
Carbon dioxide is a sufficient and important carbon resource, which has been widely used as a C1 building block in synthetic chemistry. Car- bonylations with CO are important processes in industry. However, due to the toxicity of CO, its storage and transport are problematic. Attentions are gradually focused on using other safe reagents to be the CO surrogates in carbonylation reactions. This review focuses on the summary of recent devel- opments in using CO_2 as a CO surrogate in homogeneous catalysis. Reductive processes by using H2, Si-H, alcohols, etc and redox-neutral processes are separately summarized.
基金
This work was supported by the National Natural Science Foundation of China （91745110, 21673261, 21603245, 21633013 and 21703265） and a Start-up funding from LICP. Support from the Young Elite Scientist Sponsorship Program by CAST, the CAS Interdisciplinary Innovation Team, the Key Research Program of Frontier Sciences, CAS （QYZDJ-SSW-SLH051）, and the ＇Light of West China＇ Program was also acknowledged.
