调聚反应在合成卤代烃中的应用

Application of Synthesis of Halogenated Hydrocarbons by Telomerization Reaction

调聚反应是合成卤代烃的重要途径之一,该工艺简单易行且经济高效。综述了几种主要的调聚方法,包括自由基调聚、催化调聚和辐射引发的调聚反应。特别介绍了铜催化剂、铁催化剂、镍催化剂和复合金属催化剂等几种主要调聚催化剂。

Synthesis of halogenated hydrocarbons by telomerization reaction is one of the most important routes,and the process is simple and cost-effective. In this paper,research advance on telomerization including free-radical telomerization,catalytic telomerization and radiation-initiated telomerization was reviewed,and the major telomeri-zation catalysts such as copper-based catalysts,iron-based catalysts,nickel-based catalysts and composite metal catalysts were discussed specifically.